Infrared properties of $θ$-type ET charge-transfer salts: $θ$-ET$_2$CsZn(SCN)$_4$ vs $θ$-ET$_2$RbZn(SCN)$_4$

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We performed polarized far-infrared reflectance measurements at different temperatures on $θ$-ET$_2$RbZn(SCN)$_4$ and $θ$-ET$_2$CsZn(SCN)$_4$, two typical charge-transfer salts in a series of isostructural $θ$-ET$_2$MM'(SCN)$_4$. The measurements revealed distinct differences in both electronic and vibronic spectra, which provides a clue towards understanding the different metal-insulator transitions of the two salts.
2 pages, to be published in Synthetic Metal (Proceedings of International Conference on Science and Technology of Synthetic Metals)

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