Molecular Traffic Control in a 3D network of single file channels and fast reactivity
Loading...
Date
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
Description
We study the conditions for reactivity enhancement of catalytic processes in porous solids by use of molecular traffic control (MTC) as a function of grain size. We extend a recently introduced two dimensional model system to three dimensions. With dynamic Monte-Carlo simulations and analytical solution of the associated Master equation we obtain a quantitative description of the MTC effect in the limit of fast reactivity. The efficiency ratio (compared with a topologically and structurally similar reference system without MTC) is inversely proportional to the grain diameter.
corrected affiliation
corrected affiliation